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Chemistry in
Action
The promised balanced reaction is as follows:
1. 3CH2CH2 + 2KMnO4 + H2O = 2MnO2 + 3CH3CHO +
2KOH
2. 3CH3CHO + 2KMnO4 + H2O = 3CH3COOH + 2MnO2 +
2KOH
3. 3CH3COOH + 8KMnO4 = 6CO2 + 8MnO2 + 8KOH +
2H2O
Combining equations 1-3, we get:
4. 3CH2CH2 + 12KMnO4 = 12MnO2 + 12KOH + 6CO2
Even if the reaction does not go all the way through
to the carbon dioxide-producing step, many of the
intermediate products formed either become irreversibly
bound to the media or act as reactants themselves. Such
is the case of the potassium hydroxide (KOH) formed in
equation 1 and 2. The KOH will react with the acetic
acid formed in equation 2 to produce the potassium
acetate salt (KCOOCH3) through a simple acid-base
neutralization reaction. This is shown below.
5. CH3COOH + KOH = KCOCH3 + H2O
Combining equations 1, 2, and 5 we get:
6. 3CH2CH2 + 4KMnO4 = 3KCOOCH3 + 4MnO2 + KOH
+ H2O
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